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January 1, 2018RSC AdvancesOpen Access

Unveiling Cs-adsorption mechanism of Prussian blue analogs: Cs ⁺ -percolation via vacancies to complete dehydrated state

Akira Takahashi Hisashi Tanaka Kimitaka Minami Keiko Noda Manabu Ishizaki Masato Kurihara Hiroshi Ogawa T. Kawamoto

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Key Points

The study aims to explore the mechanisms underlying Cs+ adsorption in Prussian blue analogs, focusing on factors like hydration energy and percolation.
Utilized percolation theory to analyze Cs+ adsorption capabilities.
Evaluated the hydration energy impact on ion-exchangeable site ratios.
Examined mechanisms related to vacancies in the structure.
Demonstrated a strong correlation between hydration energy and Cs+ adsorption efficiency.
Identified critical vacancy roles in facilitating ion exchange processes.
Highlighted enhanced selectivity for Cs+ in dehydrated states.

Abstract

Cs ⁺ adsorption selectivity caused by hydration energy and percolation theory to evaluate the ion-exchangeable site ratio.

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Cite This Study

Takahashi et al. (2018) studied this question.

synapsesocial.com/papers/6a6302e07adcec45b06a6fdf https://doi.org/10.1039/c8ra06377j

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