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The dry reforming of methane (DRM) is a key process for valorizing CO 2 and CH 4 , yet the catalyst longevity is limited by severe coking at low temperature. Among various catalysts studied, NiAl-based systems have been a long-standing research focus due to their inherent advantages. However, their practical application has been perpetually hampered by vulnerability to coke formation. This study investigates the effect of varying the Ni 0 /Ni 2+ ratio (from NiAl 2 O 4 ) in a 5 wt.% Ni/Al 2 O 3 catalyst, while controlling particle size and Ni dispersion, on coke resistance under conditions where carbon formation is thermodynamically favored, i.e., 600 o C, CH 4 :CO 2 :N 2 = 25:25:10, GHSV = 150 L g cat -1 h -1 . Using in situ XANES, we established that a catalyst formulation, Ni 0 /NiAl 2 O 4 /Al 2 O 3 , with 32.5% Ni 0 and 67.5% Ni 2+ achieves the highest performance. Comprehensive pulse experiments and in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) provides insights into the reaction mechanism, wherein CH x * (* adsorbed) species from CH 4 dissociation on Ni 0 are rapidly oxidized by the surface O* from NiAl 2 O 4 to form HCO 3 * and CO 3 * intermediates. Simultaneously, the CO disproportionation route to coke is suppressed. In contrast, a catalyst lacking this optimized interface readily promotes coke deposition.
Zhang et al. (Sat,) studied this question.