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The yield and final-state distributions in translational and internal degrees of freedom have been established for NO molecules desorbed from a Pd (111) surface by 200-fs pulses of 2. 0-eV photons. Among the significant characteristics of the desorption process are the large cross section and the high vibrational energy content (Tₕ>2000 K) of the desorbed molecules. A comparison with the behavior for nanosecond laser pulses indicates that a new desorption mechanism, distinct from either conventional thermal or photochemical processes, is operative in this regime.
Prybyla et al. (Mon,) studied this question.