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This article is a Perspective that introduces several review articles in the field of reversible-deactivation radical polymerizations (RDRPs), also known as living/ controlled radical polymerizations. The most important of these RDRP techniques are nitroxide-mediated polymerization (NMP), atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) polymerization and, finally, variations of organometallic-mediated polymerizations (OMRP). A brief introduction to the history and chemistry involved in each RDRP technique is given.
Devon A. Shipp (Fri,) studied this question.