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oxidation and mineralization-illustrating how spatial arrangement, co-encapsulation of catalysts and substrates, and cavity design unlock new reaction pathways under mild conditions. Mechanistic insights and structural features outline design principles for next-generation cage-based systems. Ultimately, MOCs offer molecular precision to bridge homogeneous and heterogeneous catalysis, with profound implications for the development of complex gas-liquid-solid phase reactions and transformative technologies aimed at addressing some of the most critical challenges in environmental remediation, energy generation, and circular manufacturing.
Tzunux-Tzoc et al. (Fri,) studied this question.