Key points are not available for this paper at this time.
Palladium-catalyzed carbon–carbon bond coupling reactions, the Heck and Stille reactions, proceed in supercritical carbon dioxide with a number of phosphine ligands including tris3,5-bis(trifluoromethyl)phenylphosphine, which affords high conversions and selectivities.
Morita et al. (Thu,) studied this question.