Highly Dispersed Cu−NX Moieties Embedded in Graphene: A Promising Electrocatalyst towards the Oxygen Reduction Reaction

Transition metal–carbon–nitrogen catalysts for the oxygen reduction reaction (ORR) are promising and challenging. Cu is a potential transition metal to form efficient ORR catalysts for fuel cells. Herein, a facile method is developed to synthesize a highly dispersed Cu−N X and N‐doped graphene (Cu−N−G) catalyst. The Cu−N−G catalyst shows a half‐wave potential ( E 1/2 ) of 0.859 V, which is comparable to the commercial Pt/C catalyst (0.856 V), and is among the best compared with the previously reported Cu‐based materials. In addition, such a catalyst shows good stability and methanol tolerance in alkaline media. A synergy of doped N (pyridinic and graphitic N) and Cu−N X moieties as well as the pore structure are revealed to account for the enhanced ORR activity.