Pb(II) biosorption using DAP/EDTA-modified biopolymer (Chitosan)

In this study, chitosan was chemically modified with only diammonium phosphate (DAP) and DAP/EDTA (ethylenediaminetetraacetic acid) mixture for the removal of Pb(II) ions from aqueous solution. Modified chitosan forms were analyzed using thermo-gravimetric analyzer (TGA), Fourier transform infrared (FTIR) spectroscopy, and scanning electron microscopy (SEM) to investigate the thermal degradation behavior, structural modifications, and the surface texture of the cross-linked chitosan adsorbents, respectively. The adsorption results were analyzed by well-known kinetic and isotherm models. The kinetics of metal adsorption followed the pseudo-second-order model. The maximum sorption capacities obtained from the Langmuir isotherm model were 126 mg/g for diammonium phosphate-modified Chitosan (DMC) and 137 mg/g for DAP/EDTA-modified chitosan (EDMC). The thermodynamic analysis showed that the metal removal process was endothermic in nature.