Sustainable Aviation Fuels in Aerospace Propulsion Systems: A Review from Engine Compatibility to Thermal Management

Sustainable aviation fuel is among the most practical near-term routes for aviation decarbonization because it can be used in existing aircraft, engines, and airport fuel systems with limited infrastructure changes while minimizing disruption to the aviation fuel supply chain. This review examines SAF applications in aerospace propulsion systems, focusing on production pathways, aero-engine compatibility, property prediction, and fuel heat sink potential. It compares hydroprocessed esters and fatty acids (HEFA), Fischer–Tropsch (FT), alcohol-to-jet (ATJ), synthesized iso-paraffins (SIP), and power-to-liquid (PtL) fuels in terms of feedstock type, process complexity, product composition, and blending constraints. It also assesses how molecular composition governs density, cold-flow behavior, thermal stability, coking propensity, seal compatibility, and emissions. Recent advances in molecular dynamics, machine learning, spectroscopic analysis, and uncertainty quantification show a shift from empirical estimation toward composition-based prediction, prescreening, and fuel design. For high-thermal-load propulsion systems, SAF is further evaluated as a fuel heat sink in active regenerative cooling. Current evidence points to advantages in thermal stability and low coking tendency, but important gaps remain in transcritical and supercritical heat transfer, pyrolytic heat absorption, wall-material effects, coke deposition, and heat sink capacity modeling across wide operating ranges.