Bismuth Halide Perovskite‐Like Materials: Current Opportunities and Challenges

Metal halide perovskites have recently emerged as promising photovoltaic materials for application in solar cells with high power conversion efficiencies exceeding 23 %. In the years since such high efficiencies have been attained, investigations have mainly focused on the state-of-the-art 3 D Pb-based halide perovskite materials. However, the high toxicity of Pb and intrinsic instability of the pristine perovskite materials have become great obstacles to their industrial application and commercialization. To address these serious issues, it is imperative to explore low-toxicity metal halide perovskites or their derivatives to substitute Pb-based materials for better future development. Currently, Bi-based halide perovskite-like materials are attracting increased interest as environmentally friendly alternatives for photovoltaic applications. This Concept highlights recent advances of Bi-based halide perovskite-like materials in terms of understanding and modifying their fundamental properties and related device performance, with a focus on current challenges, opportunities for future development, and diversification of device applications.