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High Resolution Image Download MS PowerPoint Slide A concise total synthesis of (+)-pedrolide has been accomplished. Key steps include an intramolecular Diels–Alder reaction to rapidly construct the tetracyclic carbon skeleton from (R)- carvone and the late-stage application of two different MHAT reactions in advancing the highly functionalized carane moiety.
Shen et al. (Mon,) studied this question.