The Raman spectra of very thin evaporated films ({~}6 nm thick) of metallic titanium and oxidized titanium are obtained with a new technique called interference-enhanced Raman scattering. The results indicate that titanium films exhibit a crystalline hcp structure while the titanium oxide has an amorphous structure with local atomic bonding configurations similar to those in crystalline Ti₂{O}₃$.
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Nemanich et al. (1980) studied this question.
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