The Effect of Temperature, Density and Chemical Composition upon the Limit of Hygroscopicity of Wood

There are several factors influencing a fundamental property of a wood species, the limit of hygroscopicity of wood (LH) or fiber saturation point (FSP). The effect of temperature upon the limit of hygroscopicity has been mentioned in literature, but has not been precisely quantified. In this paper we have correlated the LHs with temperature of thermal pretreatment, taking also into account the properties of particular wood species, i.e. density and chemical composition. For our investigation we have selected the most important domestic wood species for industrial processing : oak, beech, poplar, fir and spruce. We have determined the limits of hygroscopicity by method of compression strength parallel to grain, for the following temperature ranges of thermal treatments, in dependence of wood species : for hardwoods from 20° to 80°C and for softwoods from 20° to 90°C. Our results demonstrate the general decrease of the limit of hygroscopicity with the increase of temperature of the thermal pretreatment of the examined wood species. Mathematical correlations have been evaluated on the basis of experimental data by polynomial regression statistical method. Wood density is another factor examined as influential upon the limit of hygroscopicity. We have determined the decrease of the LH with the increase of wood density, i.e. denser wood species have lower capacity for water adsorption. The differences obtained for the LHs between the examined wood species have been explained in relation to their chemical compositions. Our results indicate that cellulose is the major wood component determining its capacity for water adsorption.