2-(Trifluoromethyl)allyl ketone O-pentafluorobenzoyloximes undergo a palladium-catalyzed 5-endo mode of alkene insertion via oxidative addition of the N-O bond, followed by beta-fluorine elimination to produce 4-difluoromethylene-1-pyrrolines.
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Ichikawa et al. (2006) studied this question.
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