October 10, 2005Angewandte Chemie International Edition206 citations
View Full PaperDiphenylphosphanylsulfoximines as Ligands in Iridium‐Catalyzed Asymmetric Imine Hydrogenations
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Abstract
Easily accessible phosphine-substituted sulfoximines 2 have been applied in Ir-catalyzed asymmetric hydrogenations of acylic N-arylated imines 1. The amines 3 are formed under mild conditions in high yields with excellent ee values.