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A new, base-free high turnover number (TON) catalyst for hydrogenation of simple and functionalized amides is prepared by reacting [Ru(η ³ -C ₃ H ₅ )(Ph ₂ P(CH ₂ ) ₂ NH ₂ ) ₂ ]BF ₄ and BH ₄ ⁻ under hydrogen.
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John et al. (2014) studied this question.
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