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A series of titanium complexes bearing [ONX] tridentate ligands have been synthesized and characterized. The complexes containing sulfur or phosphine donors showed high activity in the copolymerization of ethylene with 9-decen-1-ol (up to 1.3 × 10 8 g polymer (mol Ti) −1 h –1 ) with an incorporation ratio of up to 8.8 mol %. Moreover, they have also shown excellent capability for copolymerization of ethylene with AlBu i 3 (or tert -butylchlorodimethylsilane) pretreated 4-penten-1-ol, ω-alkenoic acid, and ω-alkenoic ester, as well as unprotected tertiary amine.
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Chen et al. (2013) studied this question.
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