Dinitrogen selectively binds to tri-coordinate Al(III) sites of the (110) termination of γ- and δ-alumina, the "defects" responsible for the low temperature dissociation of methane. Similar observations on η-Al(2)O(3) and extra framework aluminium of microporous aluminosilicates also suggest the presence of Al(III) sites on these materials.
No takes yet. Share an insight, caveat, or question.
Wischert et al. (2011) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: