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A multi-functional MOF was constructed from Cu paddlewheel motifs and a judiciously designed novel ligand bearing carboxylate, pyridine, and amide groups. exhibits selective adsorption of CO(2) over CH(4) and excellent catalytic activity in a tandem one-pot deacetalization-Knoevenagel condensation reaction as a cooperative catalyst.
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Park et al. (2012) studied this question.
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