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Abstract The photoactivation of notoriously inert sulfur hexafluoride represents a challenge for photochemistry. This short review summarizes recently published efforts and the corresponding photochemical mechanisms for switching between the fluorination and pentafluorosulfanylation reactivity of organic substrates. 1 Introduction 2 Sulfur Hexafluoride (SF6) 3 The Pentafluorosulfanyl (SF5) Group 4 Photoredox Catalytic Activation of SF6 5 Conclusions
Rombach et al. (Thu,) studied this question.