Experimental investigation reveals reactivity and transformations of adamantan-2-ylidenemalonic acid derivatives.
The acylation behavior of several nucleophiles with adamantan-2-ylidenemalonic acid dichloride was investigated. The reactivity of adamantan-2-ylidenemalonic acid and its derivatives toward reducing systems was examined. A skeletal rearrangement of adamantan-2-ylidenemalonic acid in liquid bromine was revealed, affording bromolactones possessing a protoadamantane framework.
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Merzlyakov et al. (2026) studied this question.
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