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August 2, 2026Advanced Optical Materials

Enantioresolution of Well‐Defined Au–Ag Clusters With Near‐Unity Phosphorescent Quantum Yields for Brilliant Circularly Polarized Luminescence

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Authors

WLWen‐Ting LiuPZPei ZhaoZNZi‐Ang Nan

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Overview

Randomized trial demonstrates enhanced circularly polarized luminescence in chiral metal clusters, suggesting new applications in information storage.

Key Points

  • The aim is to create chiral metal clusters with high photoluminescence and circularly polarized luminescence.
  • Enantioresolution of racemic clusters using chiral oxygen donor ligands.
  • Incorporation of ligands into carbon-centered Au6Ag6 and Au6Ag5 clusters.
  • Structural analysis and theoretical calculations to evaluate performance.
  • Phosphate-protected C@Au6Ag6 exhibited a PLQY of 0.93 and |g lum| of 0.008.
  • Three pairs of enantiopure clusters were successfully isolated demonstrating brilliant CPL.
  • Metal cluster-liquid crystal devices showed enhanced CPL for information encryption applications.

Cite This Study

Liu et al. (2026) studied this question.

synapsesocial.com/papers/6a6eeb2c1b0468a7eeab4249https://doi.org/10.1002/adom.71553
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Also Consider

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  1. 1Chirality Fixation of Ag‐Based Nanoclusters via Co‐Crystallization With Ag–P Complexes: Unlocking Circularly Polarized Luminescence2026
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  3. 3High-Performance Narrowband Circularly Polarized Luminescence Mediated by Metal Cluster2026
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