We study the capillary condensation of liquid 4He films inside narrow slit pores with a density functional model and compare the result to the predictions of the Kelvin equation. Our investigation, in the wetting situation, indicates that pores with sizes up to 100 Å are still too small for the macroscopic thermodynamic arguments used to derive the Kelvin equation to be successful. The discrepancy is tentatively attributed to the use of a slab-density model and bulk parameters in the region of very thin films.
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Cheng et al. (1993) studied this question.
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