Systems with small sizes show significant changes compared to the bulk system. These changes are of major interest regarding the size reduction of technological applications. The hydrogen‐metal system can be used as a model alloy to study small size features: shifted phase boundaries and sloped isotherms are found and, also, new materials structures. Most features can be attributed to surface‐ and interface contributions as well as to mechanical stress.
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Astrid Pundt (2004) studied this question.
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