ChemInform Abstract: Unprecedented Ring Expansion of (60)Fullerene: Incorporation of Nitrogen at an Open 6,6‐Ring Juncture by Regiospecific Reduction of Oxycarbonylaziridino(2′,3′:1,2) (60)fullerenes. Synthesis of 1a‐Aza‐1( 6a)‐homo(60)fullerene, C60H2NH.

M. R. BANKS; J. I. G. Cadogan; Ian Gosney; Andrew James Henderson; Philip Hodgson; W. G. Kerr; Andreas Kerth; Patrick R. R. Langridge‐Smith; J. R. Millar; Andrew R. Mount; John A. Parkinson; Anne Taylor; Paul Thornburn

doi:10.1002/chin.199627130

July 2, 1996ChemInform

ChemInform Abstract: Unprecedented Ring Expansion of (60)Fullerene: Incorporation of Nitrogen at an Open 6,6‐Ring Juncture by Regiospecific Reduction of Oxycarbonylaziridino(2′,3′:1,2) (60)fullerenes. Synthesis of 1a‐Aza‐1( 6a)‐homo(60)fullerene, C60H2NH.

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Key Points

Investigate a ring-expansion pathway in [60]fullerene to synthesize an aza-homofullerene derivative through selective nitrogen incorporation.
Carried out regiospecific reduction of oxycarbonylaziridino(2′,3′:1,2)[60]fullerene precursors.
Facilitated nitrogen insertion across an open 6,6-ring juncture to synthesize 1a-aza-1(6a)-homo(60)fullerene (C60H2NH).
Achieved unprecedented ring expansion of the [60]fullerene skeleton through selective chemical reduction.
Successfully isolated the nitrogen-incorporated fullerene derivative C60H2NH at an open 6,6-ring junction.

Implication

Synthetic study demonstrates nitrogen incorporation into fullerene via regiospecific reduction, revealing a novel route to aza-homofullerene derivatives.

Abstract

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Cite This Study

BANKS et al. (1996) studied this question.

synapsesocial.com/papers/6a6f5d71a7fbea1e4407b9fd https://doi.org/10.1002/chin.199627130

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ChemInform Abstract: Unprecedented Ring Expansion of (60)Fullerene: Incorporation of Nitrogen at an Open 6,6‐Ring Juncture by Regiospecific Reduction of Oxycarbonylaziridino(2′,3′:1,2) (60)fullerenes. Synthesis of 1a‐Aza‐1( 6a)‐homo(60)fullerene, C60H2NH.

Key Points

Implication

Abstract

Discussion

Cite This Study

ChemInform Abstract: Unprecedented Ring Expansion of (60)Fullerene: Incorporation of Nitrogen at an Open 6,6‐Ring Juncture by Regiospecific Reduction of Oxycarbonylaziridino(2′,3′:1,2) (60)fullerenes. Synthesis of 1a‐Aza‐1( 6a)‐homo(60)fullerene, C60H2NH.

Key Points

Implication

Abstract

Discussion

Cite This Study

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