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Two new 3D NaCl-type frameworks of [M(pyrazine)2NO2]ClO4 (M = Co, Cu), consist of (4, 4) sheets of metal-pyrazine connected by mu(1,3)-nitrito, representing the first examples of mu(1,3)-nitrito bridges and exhibiting antiferromagnetism.
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Liu et al. (2006) studied this question.
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