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August 1, 1997Inorganic Chemistry

5,10,15,20-Tetrakis(4-((pentaammineruthenio)- cyano)phenyl)porphyrinatocobalt(II) Immobilized on Graphite Electrodes Catalyzes the Electroreduction of O2 to H2O, but the Corresponding 4-Cyano-2,6-dimethylphenyl Derivative Catalyzes the Reduction Only to H2O2

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BSBeat SteigerUniversitäre Psychiatrische Dienste BernFAFred C. AnsonCalifornia Institute of Technology

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Steiger et al. (1997) studied this question.

synapsesocial.com/papers/6a6fa0dc26a7f98052dc4138https://doi.org/10.1021/ic970275o
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Also Consider

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

  1. 1Cobaltmeso-Tetrakis(N-methyl-4-pyridiniumyl)porphyrin Becomes a Catalyst for the Electroreduction of O2by Four Electrons When [(NH3)5Os]n+(n= 2, 3) Groups Are Coordinated to the Porphyrin Ring1996 · 44 citations
  2. 2New Electrocatalysts for the Four-Electron Reduction of Dioxygen Based on (5,10,15-Tris(pentaammineruthenium(II)-4-cyanophenyl)-20- (1-methylpyridinium-4-yl)porphyrinato)cobalt(II) Immobilized on Graphite Electrodes1994 · 68 citations
  3. 3Electrocatalysis of the reduction of molecular oxygen to water by tetraruthenated cobalt meso-tetrakis(4-pyridyl)porphyrin adsorbed on graphite electrodes1992 · 92 citations
  4. 4Evidence of the Importance of Back-Bonding in Determining the Behavior of Ruthenated Cyanophenyl Cobalt Porphyrins as Electrocatalysts for the Reduction of Dioxygen1995 · 44 citations
  5. 5Benzonitrile and acetonitrile complexes of ruthenium ammines1970 · 135 citations