It is shown conclusively that electron impact ionization of the C $1s$ and O $1s$ core levels of CO adsorbed on W(100) leads to CO⁺ and O⁺ desorption, respectively, and that soft-x-ray photons induce the same processes by an intrinsic photoeffect. Disintegration of the adsorption complex which becomes multiply charged by Auger decay of the core hole is assumed as explanation.
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Franchy et al. (1979) studied this question.
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