GaP (Zn, O) crystals pulled from nonstoichiometric melts by the liquid-encapsulation Czochralski (LEC) technique bridge the gap between the red photoluminescent quantum efficiencies of platelets grown from solution and crystals pulled by LEC from a stoichiometric melt. A linear correlation is shown to exist between the nonradiative shunt-path component of the total reciprocal minority-carrier lifetime and the Ga-vacancy concentration of these different crystals.
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Jordan et al. (1971) studied this question.
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