The photochemistry of santonin has an illustrious which has dealt, in the main, with the isolation, , and interrelation of the manifold formed on exposure of santonin to light in media. The established course of the reaction certain media is from santonin (I) to lumisantonin (II) and thence to photosantonic acid (IV).
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Fisch et al. (1963) studied this question.