Ion-promoted, automorphogenic, and stoichiometric self-assembly of a hexameric, Ru-based macrocycle and a dendrimer produces a stable nanofiber. A structurally related larger 3rd generation dendrimer was reacted with [(112+)(PF6−)12] to afford a neutral, sphere-like motif. These polyanionic counterions lead to ion-pair superstructures in which the randomness of single-charged counterions has been eliminated.
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Wang et al. (2008) studied this question.
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