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Polystannanes are a unique class of materials as those inorganic polymers (more precisely organometallic polymers) appear to be hitherto the only characterized polymers with a backbone of covalently bound metal atoms. This review reflects the synthesis, spectroscopic characterization (in particular (119)Sn NMR and UV-vis spectroscopy), physical properties and material properties of polystannanes, and their processing into (oriented) films and fiber blends.
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Walter Caseri (2016) studied this question.
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