Poly(dibutylstannane) and poly(dioctylstannane) were obtained by electrochemical polymerization of dibutyldichlorostannane and dioctyldichlorostannane, respectively, in a one-compartment cell equipped with a platinum cathode and a silver anode, using tetrabutylammonium perchlorate and DME as the supporting electrolyte and the solvent, respectively.
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Okano et al. (1998) studied this question.
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