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Ferrocene‐containing polymers were synthesized via addition reaction of 1,1′‐dimercaptoferrocene ( 1 ) and 1,1′‐bis(2‐mercaptoethyl)ferrocene ( 2 ) to various diolefinic monomers such as dimethacrylates, divinyl ethers, divinyl sulfones and others. The dithiol 1 was also used as a monomer in condensation reactions with bifunctional acid chlorides. The polymerization of propylene sulfide in the presence of 1 as a bifunctional initiator was found to lead to polymers with a single central ferrocene unit.
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Nuyken et al. (1996) studied this question.
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