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January 1, 2001Chemical Communications

Diastereomeric separation of [{M(Cp)(ado)}3]3+ (M = RhIII, IrIII; ado = adenosinato): crystal structure of an inclusion compound [{Rh(Cp)(ado)}3](CF3SO3)3·MeOH

Kazuaki Yamanari Rie Ito Shiori Yamamoto Akira Fuyuhiro

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Abstract

A diastereomer with a C3 cyclic trimer [{Rh(adenosine)(Cp*)}3](CF3SO3) 3, which was obtained selectively by a second-order asymmetric transformation, can include one methanol molecule into its triangle dome-like cavity.

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Yamanari et al. (2001) studied this question.

synapsesocial.com/papers/6a707f91af0c21e939284b8a https://doi.org/10.1039/b102870g

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