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A straightforward and unprecedented method towards the synthesis of 3‐silapiperidines is described. The key step involves a formal double nucleophilic substitution reaction between the (bromomethyl)dimethylsilyl chloride and a N , C ‐sp 2 ‐ 1,4‐dianionic species generated from N ‐monoprotected allylamines. Subsequent functionalizations are also presented.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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Blaszykowski et al. (2009) studied this question.
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