Electropolymerization of pyrrole or thiophene in the voids of a polystyrene colloidal crystal, followed by template removal with THF, provides a simple synthetic route to high-quality sensor-suitable, semiconducting inverse opals. Control of the film thickness is achieved by choice of the electrode potential and reaction time. The Figure shows a polythiophene inverse opal.
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Cassagneau et al. (2002) studied this question.
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