Experimental Evidence for the Curve Crossing Mechanism for Collisional Excitation in keV N₂+•/He Collisions by Emission Spectroscopy

Collision-induced emission (CIE) experiments were carried out by coupling a spectrograph and charge-coupled device detector (CCD) to a commercial analytical mass spectrometer. An Einzel lens and a deceleration-reacceleration lens assembly as described in the current article were installed in the mass spectrometer to allow for the deceleration of the ions before collision. Collision-induced emission spectra of N2+*/He collisions at lab frame collision energies from 2 to 8 keV were obtained from 190-1020 nm. The emissions were assigned to the Deltav=+2, +1, 0, -1, -2 vibrational transition progression in the N2+* B 2Sigmau+-->X 2Sigmag+ electronic transition as well as some atomic lines from the fragments N+, N* and the target gas He. N2+* A 2u-->X 2Sigmag+ emission was also observed but was very weak due to the long lifetime of the A 2u state. The relative intensities of the N2+*, N, and N+ emissions are independent of the ion translational energy within the studied energy range. This observation supports the curve-crossing mechanism for collisional excitation, suggesting that a complicated sequence of curve-crossings takes place upon collisional activation.