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The first highly stereoselective and facile synthesis ofα‐trichloromethylamines is described by using a nucleophilic trichloromethylation strategy. With tetrabutylammonium triphenyldifluorosilicate (TBAT) as the mediator, the trichloromethyl anion (CCl 3 – ) from TMSCCl 3 can be transferred to N ‐( tert ‐butylsulfinyl)aldimines in excellent yields and with high diastereoselectivity (≥99:1 dr ).
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Li et al. (2010) studied this question.
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