What question did this study set out to answer?

Establish an efficient and practical synthetic method to produce defined polyhedral hydridospherosiloxane cages, specifically Oh-H8Si8O12 and D5h-H10Si10O15.

June 1, 1991Inorganic Chemistry

New synthetic route to the hydridospherosiloxanes Oh-H8Si8O12 and D5h-H10Si10O15

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Authors

PAPradyot A. AgaskarUniversity of Illinois Urbana-Champaign

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Implication

Experimental study demonstrates a novel synthetic pathway to hydridospherosiloxanes, highlighting efficient preparation of octahedral and prismatic cage siloxanes.

Key Points

Establish an efficient and practical synthetic method to produce defined polyhedral hydridospherosiloxane cages, specifically Oh-H8Si8O12 and D5h-H10Si10O15.
Designed and executed a synthetic reaction protocol to assemble polyhedral silicon-oxygen core structures.
Isolated and characterized the resulting cubic Oh-H8Si8O12 and pentagonal prismatic D5h-H10Si10O15 siloxane frameworks.
Achieved a direct, viable synthetic pathway for isolating hydridospherosiloxanes Oh-H8Si8O12 and D5h-H10Si10O15.
Demonstrated reproducible formation of discrete octameric and decameric cage-like siloxane architectures.

Cite This Study

Pradyot A. Agaskar (1991) studied this question.

synapsesocial.com/papers/6a70a2ee2163a0a01bc4db34 https://doi.org/10.1021/ic00013a002

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Implication

Experimental study demonstrates a novel synthetic pathway to hydridospherosiloxanes, highlighting efficient preparation of octahedral and prismatic cage siloxanes.

New synthetic route to the hydridospherosiloxanes Oh-H8Si8O12 and D5h-H10Si10O15

Discussion

Member takes

Implication

Key Points

Cite This Study

New synthetic route to the hydridospherosiloxanes Oh-H8Si8O12 and D5h-H10Si10O15

Discussion

Member takes

Implication

Key Points

Cite This Study

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