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Fitting structurally on each other, the corrugated layers comprising alternately [CdNi(CN)4]∞ and H2O molecules are stacked in crystals of the title compound. Two H2O molecules coordinated trans at a Cd atom connect the layers. Six H2O molecules form a network of edge-sharing hexagons through hydrogen bonding; more H atoms are present here than can be accounted for in the formation of the maximum number of hydrogen bonds in this network.
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Park et al. (1993) studied this question.
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