A thermally stable, low‐leakage‐current, self‐aligned titanium silicide junction has now been fabricated. Ar + sputter etching of Si substrate prior to Ti film deposition followed by two‐step rapid thermal annealing in ambient are essential for realization of thermal stability up to 900°C in the titanium silicide layer. It is confirmed that the Ar + sputter etching can reduce oxygen contamination at the Ti/Si interface. Consequently the titanium silicide layer could be kept extremely flat, with 60 nm thickness with specific resistivity of 19.3 μΩ · cm, even after 900°C, 30 min annealing. The junction leakage current was less than 2.1 nA · cm −2 at reverse bias of 5.0V for n + /p junction.
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Yoshida et al. (1990) studied this question.