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January 1, 2008Dalton Transactions

Reductive elimination of C6F5–C6F5 in the reaction of bis(pentafluorophenyl)palladium(ii) complexes with protic acids

Take‐aki Koizumi Atsuko Yamazaki Takakazu Yamamoto

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Abstract

Reductive elimination of C6F5-C6F5 from cis-[Pd(C6F5)2L] (L = cod, bpy, and dppb) was promoted by Brønsted acids. HNO3 is a convenient acid for the formation of C6F5-C6F5 from [Pd(C6F5)2(cod)]. The products are controlled by the auxiliary ligand.

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Koizumi et al. (2008) studied this question.

synapsesocial.com/papers/6a70ace431a3df824328efc4 https://doi.org/10.1039/b802408a

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