⌘+K

Pulse Explore Communities Researchers Journals

Home Communities Explore

December 1, 1997Inorganic Chemistry

Synthesis of cis-Bis(heteroaryl)nickel(II) Complexes and Reductive Elimination of Bis(heteroaryl) Products Induced by Protic Acid

Yasuharu Murakami Takakazu Yamamoto

View at Publisher

Ask AI

Bookmark

Share

Abstract

Novel bis(heteroaryl)(2,2‘-bipyridyl)nickel(II) complexes have been prepared, and they have characterized by 1H NMR, elemental analysis, and X-ray crystallography. The complexes undergo reductive elimination of the heteroaryl ligands to give bipyrazoles.

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Murakami et al. (1997) studied this question.

synapsesocial.com/papers/6aa12fffff9f1d2cd5b569df https://doi.org/10.1021/ic971111a

View at Publisher

Ask AI

Bookmark

Share

Keep reading

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Nuclear magnetic resonance studies on metal complexes. Part IV. Arylnickel( II )–dimethylphenylphosphine complexesOriginal Research · 1966 · 50 citations
2Phosphine-induced reductive elimination from cis-arylmethylnickel(II) complexes having a 1,2-bis(dimethylphosphino)ethane ligandOriginal Research · 1983 · 92 citations
3Reversible oxidative addition of triphenylphosphine to zero-valent nickel and palladium complexesOriginal Research · 1976 · 109 citations
4.pi.-Conjugated Poly(pyridine-2,5-diyl), Poly(2,2'-bipyridine-5,5'-diyl), and Their Alkyl Derivatives. Preparation, Linear Structure, Function as a Ligand to Form Their Transition Metal Complexes, Catalytic Reactions, n-Type Electrically Conducting Properties, Optical Properties, and Alignment on SubstratesOriginal Research · 1994 · 467 citations
5Synthesis of Pyrazole Carboxylic Acid via Cobalt-Catalyzed Liquid Phase OxidationOriginal Research · 1991 · 10 citations

More related papers

π-Conjugated and Light Emitting Poly(4,4‘-dialkyl-2,2‘-bithiazole-5,5‘-diyl)s and Their Analogues Comprised of Electron-Accepting Five-Membered Rings. Preparation, Regioregular Structure, Face-to-Face Stacking, and Electrochemical and Optical Properties1997
X-Ray Photoelectron Spectra of Aryl-nickel Complexes1976
Organonickel(II) Complexes Containing Carbon-bonded Heterocycles as a Ligand1980

More from Inorganic Chemistry

One-Pot Synthesis of Oxidation-Resistant Silica-Coated Iron Nanoparticles via Ultrasonically Assisted Citrate ModificationThu,
Metal Composition Controls the Confined Reorientation of Nitride Clusters in Endohedral MetallofullerenesWed,