Applying Horie's method, the matrix elements of spin—other-orbit interaction for configuration d5 have been calculated. The magnetic interaction energy has also been calculated for Mn++ by means of perturbation theory. It is found that spin—other-orbit interaction plays a very important role for atoms or ions with half-filled-shell configuration. Spin—spin interaction is also significant in certain terms.
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Dunn et al. (1967) studied this question.
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