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Magnesium fluoride crystals can be grown in vacuo using the Stockbarger technique. The melting point is 1255 ± 3°C. The crystal structure is of the tetragonal SnO 2 type, with lattice constant a = 4.621 ± 0.001 Å and axial ratio 1: 0.6601 ± 0.0001 giving c = 3.050 Å at 18°C. The density is 3.1766 ± 0.0002 g cm -3 at 18°C. MgF 2 is a uniaxial positive crystal, and the refractive indices are given for the ordinary and extraordinary rays at various wavelengths in the visible spectrum. The transparent region extends from 1100 Å to 1360 cm -1 . Infra-red reflectivity begins to rise at about 620 cm -1 , and peaks around 500 cm -1 . The mean dielectric constant is m = 5.26.
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Duncanson et al. (1958) studied this question.
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