What question did this study set out to answer?

Synthesize and structurally characterize group 11 transition metal complexes of copper, silver, and gold coordinated with 3,5-diphenylpyrazole and 3,5-diphenylpyrazolate ligands.

January 1, 1988Inorganic Chemistry

Syntheses and x-ray structures of group 11 pyrazole and pyrazolate complexes. X-ray crystal structures of bis(3,5-diphenylpyrazole)copper(II) dibromide, tris(.mu.-3,5-diphenylpyrazolato-N,N')trisilver(I)-2-tetrahydrofuran, tris(.mu.-3,5-diphenylpyrazolato-N,N')trigold(I), and hexakis(.mu.-3,5-diphenylpyrazolato-N,N')hexagold(I)

View Full Paper

Ask AI

Bookmark

Authors

HMH. H. MurrayVirginia Tech RRRaphael G. RaptisFlorida International University JFJohn P. FacklerTexas A&M University

Discussion

Member takes

Implication

Crystallographic study reveals distinct nuclearities in group 11 pyrazolate complexes, highlighting diverse coordination geometries across copper, silver, and gold.

Key Points

Synthesize and structurally characterize group 11 transition metal complexes of copper, silver, and gold coordinated with 3,5-diphenylpyrazole and 3,5-diphenylpyrazolate ligands.
Synthesized coordination compounds combining copper(II), silver(I), and gold(I) precursors with 3,5-diphenylpyrazole or its deprotonated pyrazolato form.
Determined solid-state structures and coordination geometries using single-crystal X-ray diffraction.
Determined the monomeric coordination structure of bis(3,5-diphenylpyrazole)copper(II) dibromide.
Resolved trimeric cyclic frameworks for tris(μ-3,5-diphenylpyrazolato-N,N')trisilver(I) and trigold(I), alongside a hexanuclear hexagold(I) metallacycle.

Cite This Study

Murray et al. (1988) studied this question.

synapsesocial.com/papers/6a70d11cb5c1fe5ca9dfc20d https://doi.org/10.1021/ic00274a008

View Full Paper

Ask AI

Bookmark

Implication

Crystallographic study reveals distinct nuclearities in group 11 pyrazolate complexes, highlighting diverse coordination geometries across copper, silver, and gold.

Discussion

Member takes

Implication

Key Points

Cite This Study

Discussion

Member takes

Implication

Key Points

Cite This Study

Also Consider

Also Consider