A correlation has been fround between the stereochemistry of 3‐methoxyeyclopentyl and 3‐methoxyccyelohexyl acetic acid esters and their methane or isobutane themical ionizaion spectra: only the cis compounds yield quasimolecular ions and the [MHCH 3 OH] + ions are more abundant for the trans isomers. A similar situation occurs in the iow temperature methane chemical ionization spectra of the coresponding trimethylsilylethers.
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Gaever et al. (1977) studied this question.
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