Neutral triazacyclononane−amide lanthanum dialkyl and dialkynyl complexes were synthesized and structurally characterized. A cationic triazacyclononane−amide lanthanum monoalkyl species was generated and found to be highly active (tof > 100 h - 1 ) in the rare cis-selective catalytic linear dimerization of phenylacetylene.
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Tazelaar et al. (2004) studied this question.
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