N-(Trifluoromethylsulfonyl)trifluoromethanesulfonimidoyl fluoride 4 was prepared by the oxidative fluorination of N-(trifluoromethylsulfinyl)trifluoromethanesulfonamides 3a,b which are formed by the reaction of trifluoromethyltrimethylsilane with N-(sulfinyl)trifluoromethanesulfonamide in the presence of fluoride ions. Addition of MF to N-(sulfinyl)trifluoromethanesulfonamides affords the stable N-(fluorosulfinyl)trifluoromethanesulfonamides 2a,b. Reaction of 4 with N-nucleophiles readily forms the corresponding amides 6–8.
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Garlyauskayte et al. (2002) studied this question.
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